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Title: US7422667: Electrochemical deposition of carbon nanoparticles from organic solutions
[ Derwent Title ]


Country: US United States of America

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Inventor: Zhou, Dan; St. Peter, MO, United States of America
Chow, Lee; Orlando, FL, United States of America
Anoshkina, Elvira Vladimirovna; Winter Springs, FL, United States of America

Assignee: University of Central Florida Research Foundation, Inc., Orlando, FL, United States of America
other patents from UNIVERSITY OF CENTRAL FLORIDA (599435) (approx. 135)
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Published / Filed: 2008-09-09 / 2004-10-18

Application Number: US2004000699488

IPC Code: Advanced: C25B 3/00; C25B 9/06; B82B 3/00;

U.S. Class: 204/230.1; 204/229.8; 204/242; 977/742; 977/842; 977/899;

Field of Search: 205/202

Abstract:     Carbon nanoparticles including both nanofilaments and nanotubes produced by an electrochemical deposition method from organic solutions at room temperature, in which the formation and growth of carbon nanoparticles are stimulated by the catalyst, such as iron and nickel. It has been found that the electrochemical deposition conditions have a strong influence on the growth phenomenon of the carbon nanotubes. Scanning electron microscope (SEM) and transmitting electron microscope (TEM) characterizations show that the diameter of nanotubes is of the order of approximately 100 nm, and the length of filaments can be up to approximately 50 μm, depending on the size of catalyst particles.

Attorney, Agent or Firm: Steinberger, Brian S. ; Morlin, Joyce ; Law Offices of Brian S. Steinberger, P.A. ;

Primary / Asst. Examiners: Wilkins, III, Harry D;

INPADOC Legal Status: Show legal status actions

       
Related Applications:
Application Number Filed Patent Pub. Date  Title
US2002000119414 2002-04-09    2004-07-06  Electrochemical deposition of carbon nanoparticles from organic solutions


       
Family: None

First Claim:
Show all 3 claims
    1. An electrochemical deposition apparatus for producing carbon nanoparticles comprising the components of:

(a) a container having a closed bottom portion and an open top portion, suitable for housing a liquid hydrocarbon selected from at least one of methanol, and benzyl alcohol and mixtures thereof;

(b) a silicon wafer anode and a silicon wafer cathode each coated with catalytic nanoparticles of iron and nickel, wherein the anode and cathode are spaced apart and positioned in the bottom portion of the container as two electrodes in a plurality of electrodes in said container;

(c) a magnetic stirrer for agitating the liquid hydrocarbon in the container; and

(d) a power supply with an ammeter and a voltmeter connected between the anode and the cathode for imposing a direct current potential of approximately 1000 volts between the two electrodes and providing a current density of approximately 12 miliamps per square centimeter between the two electrodes for a time sufficient that carbon nanoparticles are deposited on said the two electrodes, wherein each of the carbon nanoparticles includes:

a nanotube produced from the organic solution under ambient conditions having a diameter ranging from approximately 50 nm to approximately 100 nm and a length ranging from approximately 2 nm to approximately 50 μm.



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U.S. References: Go to Result Set: All U.S. references   |  No patents reference this one   |   Backward references (15)   |   Citation Link

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PDF
Patent  Pub.Date  Inventor Assignee   Title
Buy PDF- 6pp US4310393  1982-01 Bell  General Electric Company Electrochemical carbonate process
Buy PDF- 6pp US4472533  1984-09 Moskovitis  The University of Toronto Innovations Foundation Heterogeneous catalyst and process for its manufacture
Buy PDF- 10pp US5690807  1997-11 Clark  Massachusetts Institute of Technology Method for producing semiconductor particles
Buy PDF- 6pp US5693207  1997-12 Fromson  Fromson; Howard A. Catalyst preparation
Buy PDF- 25pp US5973444  1999-10 Xu et al.  Advanced Technology Materials, Inc. Carbon fiber-based field emission devices
Buy PDF- 10pp US6129901  2000-10 Moskovitis et al.  Moskovits; Martin Controlled synthesis and metal-filling of aligned carbon nanotubes
Buy PDF- 14pp US6146227  2000-11 Mancevski  Xidex Corporation Method for manufacturing carbon nanotubes as functional elements of MEMS devices
Buy PDF- 11pp US6361660  2002-03 Goldstein   Photoelectrochemical device containing a quantum confined group IV semiconductor nanoparticle
Buy PDF- 14pp US6638413  2003-10 Weinberg et al.  Lectro Press, Inc. Methods and apparatus for electrolysis of water
Buy PDF- 55pp US6650061  2003-11 Urayama et al.  Sharp Kabushiki Kaisha Electron-source array and manufacturing method thereof as well as driving method for electron-source array
Buy PDF- 38pp US6838297  2005-01 Iwasaki et al.  Canon Kabushiki Kaisha Nanostructure, electron emitting device, carbon nanotube device, and method of producing the same
Buy PDF- 5pp US20020150684A1  2002-10 Jayatissa   Method of forming carbon nanotubes and apparatus therefor
Buy PDF- 54pp US20020159943A1  2002-10 Smalley et al.   Method for forming an array of single-wall carbon nanotubes and compositions thereof
Buy PDF- 125pp US20020172968A1  2002-11 Kudo   Biochips comprising nucleic acid/protein conjugates
Buy PDF- 19pp US20030102222A1  2003-06 Zhou et al.   Deposition method for nanostructure materials
       
Foreign References: None

Continuity Data:
Application Number Filed Notes

US2003000699488   is a division of
US2002000119414  2002-04-09
     US6758957 issued 2004-07-06   Electrochemical deposition of carbon nanoparticles from organic solutions

US2004000699488 2004-10-18  is a non-provisional of provisional
US2001000284360P  2001-04-17


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