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Title: US4537612: Colored photochromic glasses and method
[ Derwent Title ]


Country: US United States of America

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27 pages

 
Inventor: Borrelli, Nicholas F.; Elmira, NY
Hares, George B.; Corning, NY
Smith, Dennis W.; Corning, NY
Wedding, Brent M.; Corning, NY

Assignee: Corning Glass Works, Corning, NY
other patents from CORNING INCORPORATED (123425) (approx. 3,659)
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Published / Filed: 1985-08-27 / 1984-09-17

Application Number: US1984000650846

IPC Code: Advanced: C03C 4/06; C03C 21/00; C03C 23/00;
Core: C03C 4/00; more...
IPC-7: C03C 3/26; C03C 21/00;

U.S. Class: Current: 065/030.11; 501/013;
Original: 065/030.11; 501/013;

Field of Search: 065/30.11,32 501/013

Priority Number:
1984-09-17  US1984000650846
1982-04-01  US1982000364472

Abstract: This invention is directed to a method for modifying the coloration produced in a silver halide-containing photochromic glass when heat treating the glass at a temperature not exceeding 450° C. under reducing conditions. The method comprises subjecting such a glass having a base composition which contains at least 1% by weight Li2 O, at least 2% by weight Na2 O, and at least 6% by weight Li2 O+Na2 O+K2 O to an ion exchange reaction, wherein lithium ions, and potassium ions, when the latter are present in the composition, in the glass surface are exchanged with sodium ions from an external source, prior to the reduction heat treatment.

Attorney, Agent or Firm: Janes, Jr., C. S. ;

Primary / Asst. Examiners: Schor, Kenneth M.;

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Related Applications: Go to Result Set: 1 patent(s) that list this one as related
Application Number Filed Patent Pub. Date  Title
US1982000364472 1982-04-01       


       
Parent Case:     This application is a continuation-in-part of application Ser. No. 364,472, filed Apr. 1, 1982 now abandoned.

Designated Country: DE FR GB 

Family: Show 7 known family members

First Claim:
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We claim:     1. A method for producing a permanent coloration in a surface zone on a photochromic glass article wherein silver halide is the photochromic agent, wherein the glass composition contains at least 1% by weight Li2 O, at least 2% by weight Na2 O, and at least 6% by weight Li2 O+Na2 O+K2 O, and wherein the glass article is heat treated at a temperature not exceeding about 450° C. under reducing conditions for a time at least sufficient to modify the light absorption characteristics of the article surface, the improvement comprising shifting the optical absorption band imparted to the article during the reduction treatment by (1) changing the content of said Na2 O in at least a portion of the surface coloration zone of the article by exchanging lithium ions and potassium ions from within the glass surface sodium ions from an external source, said exchanging being effected prior to said reduction treatment and by (2) controlling the conditions of and the extent of ion exchange such that said shifting will be effected to provide a new absorption band.

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Forward References: Show 20 U.S. patent(s) that reference this one

       
U.S. References: Go to Result Set: All U.S. references   |  Forward references (20)   |   Backward references (3)   |   Citation Link

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PDF
Patent  Pub.Date  Inventor Assignee   Title
Get PDF - 11pp US4018965  1977-04 Kerko et al.  Corning Glass Works Photochromic sheet glass compositions and articles
Get PDF - 9pp US4240836  1980-12 Borrelli et al.  Corning Glass Works Colored photochromic glasses and method
Get PDF - 8pp US4284686  1981-08 Wedding  Corning Glass Works Spectacle lenses to reduce discomfort from aphakia and certain eye diseases
       
Foreign References:
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PDF
Publication Date IPC Code Assignee   Title
Buy PDF SU0604837 1978-04  C03C 21/00 LE T I TSELLYULOZNO-BUMAZHNOJ PROMYSHLENNOSTI METHOD OF MANUFACTURING PHOTOCHROMIC GLASS 


Other Abstract Info: CHEMABS 099(26)217462F

Other References:
  • Kozlowski et al.; American Journal of Optometry, vol. 50, No. 4, Apr. 1973, pp. 79-88.


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