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Title: US5496649: Cross-linked PVOH coatings having enhanced barrier characteristics
[ Derwent Title ]


Country: US United States of America

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6 pages

 
Inventor: Mallory, William M.; Farmington, NY
Bianchini, Eber C.; Rochester, NY

Assignee: Mobil Oil Corp., Fairfax, VA
other patents from MOBIL OIL CORP. (381140) (approx. 7,205)
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Published / Filed: 1996-03-05 / 1994-07-21

Application Number: US1994000278458

IPC Code: Advanced: B32B 27/30; C08F 8/28; C08J 3/03; C08J 7/04; C08K 5/07; C08L 29/04;
Core: C08F 8/00; C08J 3/02; C08J 7/00; C08K 5/00; C08L 29/00; more...
IPC-7: B05D 3/04; B32B 27/08; C08K 3/22;

ECLA Code: C08J3/03+L29/04; C08J7/04L29;

U.S. Class: Current: 428/518; 427/340; 427/393.5; 427/412.3; 428/461; 428/512; 428/513; 428/516; 428/910; 525/056; 525/061;
Original: 428/518; 428/516; 428/910; 428/512; 428/513; 428/461; 427/340; 427/393.5; 427/412.3; 525/056; 525/061;

Field of Search: 428/518,910,516 427/340,393.5,412.3 525/056,61

Priority Number:
1994-07-21  US1994000278458

Abstract: An improved oxygen barrier layer for coating a substrate, such as a polymeric film. The oxygen barrier is a layer of cross-linked polyvinyl alcohol and glyoxal, which exhibits improved barrier characteristics to the transmission of oxygen. The oxygen barrier is produced by coating a solution of polyvinyl alcohol, glyoxal and tensoactive agent onto at least one side of a substrate adapted for receipt of such solution. The polyvinyl alcohol is thereafter cross-linked in the absence of a catalyst to provide the oxygen barrier.

Attorney, Agent or Firm: McKillop, Alexander J. ; Santini, Dennis P. ;

Primary / Asst. Examiners: Sluby, P. C.;

Maintenance Status: E2 Expired  Check current status
CC Certificate of Correction issued

INPADOC Legal Status: Show legal status actions          Buy Now: Family Legal Status Report

Designated Country: AU CA EP JP KP NZ 

Family: Show 15 known family members

First Claim:
Show all 16 claims
What is claimed is:     1. A method of providing an improved moisture-resistant oxygen barrier onto a surface of a substrate comprising:
  • coating said surface of said substrate with a solution of poly(vinyl alcohol), glyoxal and a C4 to C10 alcohol, wherein said solution includes an amount of glyoxal sufficient to substantially 100% crosslink said poly(vinyl alcohol) and from about 5 ppm to about 0.5% by weight of said alcohol; and
  • drying said coated substrate to substantially 100% crosslink said poly(vinyl alcohol) in the absence of a catalyst to provide said moisture-resistant oxygen barrier.


Background / Summary: Show background / summary

Drawing Descriptions: Show drawing descriptions

Description: Show description

Forward References: Show 8 U.S. patent(s) that reference this one

       
U.S. References: Go to Result Set: All U.S. references   |  Forward references (8)   |   Backward references (27)   |   Citation Link

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PDF
Patent  Pub.Date  Inventor Assignee   Title
Buy PDF- 3pp US3518242  1970-06 Chrisp   POLYVINYL ALCOHOL AND DERIVATIVES CROSSLINKED WITH TITANIUM,PERMANGANATE,OR VANADYL IONS
Buy PDF- 2pp US3702844  1972-11 Ofstead et al.   POLYVINYL ALCOHOL-PHOSPHORIC ACID FILMS
Buy PDF- 6pp US3719621  1973-03 Vogt et al.   PROCESS FOR PREPARING POLYURETHANES IN AN ISOCYANATE-REACTIVE SOLVENT SOLUTION
Buy PDF- 4pp US4154912  1979-05 Philipp et al.  The United States of America as represented by the Administrator of the National Aeronautics and Space Administration In situ self cross-linking of polyvinyl alcohol battery separators
Buy PDF- 7pp US4214039  1980-07 Steiner et al.  Mobil Oil Corporation Polypropylene film with primer of a water dispersed epoxy resin coating
Buy PDF- 4pp US4224262  1980-09 Baird, Jr. et al.  W. R. Grace & Co. Crosslinked copolymer of an olefin and vinyl alcohol
Buy PDF- 7pp US4235365  1980-11 Yoshii et al.  Toray Industries, Inc. Three-layered polypropylene films
Buy PDF- 4pp US4240993  1980-12 Sun  W. R. Grace & Co. Multi-layer film containing a layer of crosslinked ethylene/vinyl alcohol copolymer
Buy PDF- 5pp US4254169  1981-03 Schroeder  American Can Company Multi-layer barrier film
Buy PDF- 4pp US4262067  1981-04 Phillipp et al.  The United States of America as represented by the Administrator of the National Aeronautics and Space Administration In-situ cross linking of polyvinyl alcohol
Buy PDF- 4pp US4272470  1981-06 Hsu et al.  The United States of America as represented by the Administrator of the National Aeronautics and Space Administration Cross-linked polyvinyl alcohol and method of making same
Buy PDF- 4pp US4275119  1981-06 Weiner  Mobil Oil Corporation Heat sealable packaging film comprising propylene polymer substrate and a surface layer blend of olefin copolymer or interpolymer
Buy PDF- 3pp US4276330  1981-06 Stanley et al.  Crown Zellerbach Corporation Trilaminate film for forming sideweld bags
Buy PDF- 4pp US4277572  1981-07 Fujiwara et al.  The Furukawa Electric Company, Ltd. Galvanic cell separator
Buy PDF- 7pp US4284671  1981-08 Cancio et al.  Clopay Corporation Polyester compositions for gas and moisture barrier materials
Buy PDF- 6pp US4288477  1981-09 Bordini et al.  Moplefan S.p.A. Readily thermoweldable films of polyolefins coated with lacquers based on ketonic resins
Buy PDF- 6pp US4357402  1982-11 Sheibley et al.  The United States of America as represented by the Administrator of the National Aeronautics and Space Administration Polyvinyl alcohol cross-linked with two aldehydes
Buy PDF- 6pp US4376183  1983-03 Haskell  E. I. Du Pont de Nemours and Company Inorganic films with poly(vinyl alcohol) and coating compositions for making them
Buy PDF- 6pp US4416938  1983-11 Haskell  E. I. Du Pont de Nemours & Co. Inorganic films with poly(vinyl alcohol)
Buy PDF- 6pp US4439493  1984-03 Hein et al.  Mobil Oil Corporation Multilayer heat sealable oriented packaging film and method of forming same
Buy PDF- 6pp US4475241  1984-10 Mueller et al.  American Can Company Polycarbonate coated films
Buy PDF- 5pp US4564559  1986-01 Wagner, Jr. et al.  Mobil Oil Corporation Oriented multi-layer heat sealable film
Buy PDF- 3pp US4650721  1987-03 Ashcraft  Mobil Oil Corporation Polypropylene barrier film and method of forming same
Buy PDF- 6pp US4725646  1988-02 Kobashi et al.  Japan Exlan Company, Limited Method of producing hard polyvinyl alcohol gel
Buy PDF- 4pp US4785049  1988-11 Balaba et al.  Aluminum Company of America Forming clear gel and transparent film by reacting alumina hydrate with vinyl alcohol-vinyl acetate copolymer
Buy PDF- 7pp US4927689  1990-05 Markiewicz  Du pont Canada Inc. Gas barrier structures
Buy PDF- 3pp US5230963  1993-07 Knoerzer  Mobil Oil Corporation Oxygen and water vapor transmission resistant film and method
       
Foreign References: None

Other Abstract Info: CHEMABS 124(26)346210F DERABS C96-151018

Other References:
  • T. W. Modi, Polyvinyl Alcohol, in Handbook of Water-Soluble Gums and Resins 20.1-20.32 (Robert L. Davidson ed., 1980).
  • Harold L. Jaffe and Franklin M. Rosenblum, Poly(Vinyl Alcohol) for Adhesives, in Handbook of Adhesives 401-407 (Irving Skeist ed., 1990).


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