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Title: US4459338: Method of deposition of silicon carbide layers on substrates and product
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Country: US United States of America

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6 pages

 
Inventor: Angelini, Peter; Oak Ridge, TN
DeVore, Charles E.; Knoxville, TN
Lackey, Walter J.; Oak Ridge, TN
Blanco, Raymond E.; Oak Ridge, TN
Stinton, David P.; Knoxville, TN

Assignee: The United States of America as represented by the United States Department of Energy, Washington, DC
other patents from UNITED STATES OF AMERICA, DEPARTMENT OF ENERGY (597195) (approx. 6,712)
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Published / Filed: 1984-07-10 / 1982-03-19

Application Number: US1982000360116

IPC Code: Advanced: C23C 16/32; G21F 9/34;
Core: more...
IPC-7: B32B 5/16; B32B 9/00;

U.S. Class: Current: 428/404; 427/215; 427/249.15; 428/218; 976/DIG.394;
Original: 428/404; 427/215; 427/249; 427/255; 428/218;

Field of Search: 427/249,95,255.1,255.7,215,255 428/446,448,404,218

Government Interest:     The invention is a result of a contract with the U.S. Department of Energy.

Priority Number:
1982-03-19  US1982000360116

Abstract: A method for direct chemical vapor deposition of silicon carbide to substrates, especially nuclear waste particles, is provided by the thermal decomposition of methylsilane at about 800° C. to 1050° C. when the substrates have been confined within a suitable coating environment.

Attorney, Agent or Firm: Larcher, Earl L. ; Hamel, Stephen D. ; Esposito, Michael F. ;

Primary / Asst. Examiners: Childs, Sadie L.;

Maintenance Status: E2 Expired  Check current status

INPADOC Legal Status: Show legal status actions

Family: None

First Claim:
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What is claimed is:     1. A method for providing a nuclear waste particle with a coating consisting of crystalline silicon carbide directly on exposed surfaces thereof, comprising the steps of contacting the particle with a gaseous mixture of methylsilane in an inert gas selected from the group consisting of argon, helium, nitrogen and mixtures thereof while concurrently heating the gaseous mixture and the particle to a temperature in the range of about 800° to 1,050° C. to effect the thermal decomposition of the methylsilane for providing carbon and silicon donors for forming silicon carbide and the chemical vapor deposition of these carbon and silicon donors onto said exposed surfaces as an essentially uniform coating of crystalline silicon carbide on said particle.

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Forward References: Show 11 U.S. patent(s) that reference this one

       
U.S. References: Go to Result Set: All U.S. references   |  Forward references (11)   |   Backward references (3)   |   Citation Link

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Patent  Pub.Date  Inventor Assignee   Title
Buy PDF- 3pp US3382113  1968-05 Ebert et al.   METHOD OF EPITAXIALLY GROWING SILICON CARBIDE BY PYROLYTICALLY DECOMPOSING SIH4 AND CH4
Buy PDF- 4pp US3386866  1968-06 Ebert et al.   METHOD OF EPITAXIALLY GROWING A LAYER OF SILICON CARBIDE ON A SEED BY PYROLYTIC DECOMPOSITION OF HYDROCARBONS OR MIXTURES OF SILANES AND HYDROCARBONS
Buy PDF- 2pp US3736169  1973-05 Graham et al.   PYROLYTIC DEPOSITION PROCESS FOR APPLYING A MULTI-LAYER COATING TO A NUCLEAR FUEL KERNEL
       
Foreign References:
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Publication Date IPC Code Assignee   Title
Buy PDF DE2157145 1972-05  C04B 37/00 PLESSEY HANDEL UND INVESTMENTS AG VERBUNDKOERPER UND VERFAHREN ZU SEINER HERSTELLUNG 


Other Abstract Info: CHEMABS 101(14)119200J CAN101(14)119200J

Other References:
  • Marinare, "Thin Films of a Silicon-Carbon Compound", IBM Tech. Discl. Bulletin, vol. 17, No. 10, Mar. 1975.
  • Lauf et al., "Characterization of SiC Coatings on HTGR Fuel Particles", Union Carbide Corp., Jan. 1981.


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